Removal of Anionic Surfactant from Residential Laundry Wastewater using Jackfruit (Artocarpus heterophyllus) seeds

Document Type : Research Paper


1 Department of Chemistry, College of Natural Sciences, Jimma University, P. O. Box 378, Jimma, Ethiopia.

2 Department of Environmental Health Sciences and Technology, Public Health Faculty, Institute of Health Sciences, Jimma University, Jimma, Ethiopia


The study presented in this article investigated the removal of a long chain anionic surfactant from residential laundry wastewater using jackfruit (Artocarpus heterophyllus) seeds. The main ingredients of laundry wastewater are the surfactants. Therefore, great attention should be given to the treatment and disposal of laundry wastewater. The use of natural substitutes in treating wastewater has no harmful effects, and it is considered an effective step towards protecting the environment and promoting sustainability. Jar test experiments were conducted in order to determine the optimum conditions for the removal of surfactants, chemical oxygen demand (COD), biological oxygen demand (BOD), turbidity in terms of effective dosage, and pH control. The surfactant, COD, BOD, and turbidity removal efficiencies were 91.66%, 82.86%, 77.66%, and 85.14% at the optimum initial pH value of 6, the optimum dose of 2.5 g/L, and optimum mixing time of 25 minutes, respectively. It can be concluded that Artocarpus heterophyllus seed powder was a feasible and cost-effective natural coagulant for the removal of anionic surfactant from laundry wastewater. The results showed that the pseudo-second-order equation is the suitable model for this system.


Main Subjects

[1] Krishnan, S., Chandran, K., Sinnathamb, C. M. (2016). Wastewater treatment technologies used for the removal of different surfactants: A comparative review. International journal of applied chemistry, 12, 727–739.
[2] Siyal, A. A., Shamsuddin, M. R., Low, A., Rabat, N. E. (2020). A review on recent developments in the adsorption of surfactants from wastewater. Journal of Environmental Management, 254, 109797-109811.
[3] Ikehata, K., El-Din, M. G. (2004). Degradation of recalcitrant surfactants in wastewater by ozonation and advanced oxidation processes: A review. Ozone: science and engineering, 26, 327-343.
[4] Tripathi, S. K., Tyagi, R., Nandi, B. K. (2013). Removal of residual surfactants from laundry wastewater: A review. Journal of dispersion science and technology, 34, 1526-1534.
[5] Aboulhassan, M. A., Souabi, S., Yaacoubi, A., Baudu, M. (2006). Removal of surfactant from industrial wastewaters by coagulation flocculation process. International journal of environmental science and technology, 3 327-332.
[6] Nguyen, H. M., Phan, C., Sen, T., Hoang, A. (2015). TOC removal from laundry wastewater by photoelectrochemical process on Fe2O3 nanostructure. Desalination and water treatment, 57, 14379-14385.
[7] Jangkorn, S., Kuhakaew, S., Theantanoo, S., Klinla-or, H., Sriwiriyarat, T. (2011). Evaluation of reusing alum sludge for the coagulation of industrial wastewater containing mixed anionic surfactants. Journal of environmental sciences, 23, 587-594.
[8] Sima, J., Havelkab, M., Holcova, V. (2009). Removal of Anionic Surfactants from wastewater using a constructed wetland. Chemistry and biodiversity, 6, 1350-1363.
[9] Rao, C. S. (1995). . Environmental pollution control engineering, Wiley Eastern Ltd.
[10] Kowalska, I., Klimonda, A., Application of nanofiltration membranes for removal of surfactants from water solutions. In E3S Web of conferences 2017; Vol. 17, p 00044.
[11] Ríos, F., Olak-Kucharczyk, M., Gmurek, M., Ledakowicz, S. (2017). Removal efficiency of anionic surfactants from water during UVC photolysis and advanced oxidation process in H2O2/UVC system. Archives of environmental protection, 43, 20-26.
[12] Endang Tri Wahyuni, R. Roto, M. Sabrina, V. Anggraini, N. F. L., Vionita, A. C. (2016). Photodegradation of Detergent Anionic Surfactant in Wastewater Using UV/TiO2/H2O2 and UV/Fe2+/H2O2 Processes. American journal of applied chemistry,  4, 174–180.
[13] Mozia, S., Tomaszewska, M., Morawski, A. W. (2005). Decomposition of nonionic surfactant in a labyrinth flow photoreactor with immobilized TiO2 bed. Applied catalysis B: Environmental, 59, 155-160.
[14] Fernández, E., Benito, J. M., Pazos, C., Coca, J. (2005). Ceramic membrane ultrafiltration of anionic and nonionic surfactant solutions. Journal of membrane science, 246, 1-6.
[15] Borchate, S. S., Smita, S., Kulkarni, G. S., Kore, S. V., Kore, V. S. (2012). Application of coagulation- flocculation for vegetable tannery wastewater. International journal of engineering science and technology 4, 1944-1948.
[16] Chen, X., Chen, G., Yue Po, L. (2000). Separation of pollutants from restaurant wastewater by electrocoagulation. Separation and purification technology, 19, 65-76.
[17] Bratby, J. (2006). Coagulation and flocculation in water and wastewater treatment. IWA publishing: London, Seattle.
[18] Tekade, P. V., Mohabansi, N. P., Patil, V. B. (2011). Study of physico-chemical properties of effluents from soap industry in wardha. Rasayan journal of chemistry, 4(2), 461-465.
[19] Merrettig-Bruns, U., Jelen, E. (2009). Anaerobic biodegradation of detergent surfactants. Materials, 2(1), 181-206.
[20] Ronke, R. A., Saidat, O. G., Abdulwahab, G. (2016). Coagulation-flocculation treatment of industrial wastewater using Tamarind seed powder. International journal of ChemTech research, 9(5), 771-780.
[21] Jouanneau, S., Recoules, L., Durand, M. J., Boukabache, A., Picot, V., Primault, Y., Thouand, G. (2014). Methods for assessing biochemical oxygen demand (BOD): A review. Water research, 49, 62-82.
[22] Jurado, E., Fernández-Serrano, M., Nunez-Olea, J., Luzon, G., Lechuga, M. (2006). Simplified spectrophotometric method using methylene blue for determining anionic surfactants: applications to the study of primary biodegradation in aerobic screening tests Chemosphere, 65(2), 278-285.
[23] FDRE, E. P. A. Environmental Impact Assessment Procedural guideline series 1. December 2003. Addis Ababa.
[24] Loiskandl, W., Awulachew, S. B., Boelee, E. (2010). Evaluation of the environmental policy and impact assessment process in Ethiopia. Impact assessment and project appraisal, 28, 29-40.
[25] Aonyas, M. M., Dojčinović, B. P., Dolić, S. D., Obradović, B. M., Manojlović, D. D., Marković, M. D.,Roglić, G. M. (2016). Degradation of anionic surfactants using the reactor based on dielectric barrier discharge. Journal of the serbian chemical society, 81, 1097-1107.
[26] Muhammad, R. R. K., Muhammad K. D., Lim, L. B. (2016). Jackfruit seed as a sustainable adsorbent for the removal of Rhodamine B dye. Journal of environment and biotechnology research, 4, 7–16.
[27] Alhamed, Y. A. (2006). Activated Carbon from dates' stone by ZnCl2 activation. Engineering science, 17. 75-98.
[28] Hayashi, J. K., A., Muroyama, K., Watkinson, A. P. (2000). Preparation of activated Carbon from lignin by chemical activation. Carbon, 38, 1873-1878.
[29] Beltrán-Heredia, J., Sánchez-Martín, J., Solera-Hernández, C. (2009). Anionic surfactants removal by natural coagulant/flocculant products. Industrial and engineering chemistry research, 48, 5085-5092.
[30] Thirugnanasambandan, T., Venkadamanickam, G., Palanivelu, M., Alagar, M. (2011). Nano sized powder of jackfruit Seed: Spectroscopic and anti-microbial investigative approach. Nano biomedicine and engineering, 3, 215-221.
[31] Beltrán-Heredia, J., Sánchez-Martín, J.,Barrado-Moreno, M. (2012). Long-chain anionic surfactants in aqueous solution. Removal by Moringa oleifera coagulant. Chemical engineering journal, 180, 128-136.
[32] Ndabigengesere, A., Narasiah, K. S., Talbot, B. G. (1995). Active agents and mechanism of coagulation of turbid waters using Moringa oleifera. Water research, 29, 703-710.
[33] Miller, S. M., Fugate, E. J., Craver, V. O., Smith, J. A., Zimmerman, J. B. (2008). Toward understanding the efficacy and mechanism of Opuntia spp. as a natural coagulant for potential Application in water treatment. Environmental science and technology,  42, 4274-4279.
[34] Abebe, L. S., Chen, X., Sobsey, M. D. (2016). Chitosan coagulation to improve microbial and turbidity removal by ceramic water filtration for household drinking water treatment. International journal of environmental research and public health, 13, 269-280.
[35] Ayranci, E., Duman, O. (2007). Removal of anionic surfactants from aqueous solutions by adsorption onto high area activated carbon cloth studied by in situ UV spectroscopy. Journal of hazardous materials, 148, 75-82.
[36] Prediger, P., Cheminski, T., de Figueiredo Neves, T., Nunes, W. B., Sabino, L., Picone, C. S. F., Oliveira, R. L., Correia, C. R. D. (2018). Graphene oxide nanomaterials for the removal of non-ionic surfactant from water. Journal of environmental chemical engineering, 6, 1536-1545.
[37] Antov, M. G., Šćiban, M. B., Prodanović, J. M. (2012). Evaluation of the efficiency of natural coagulant obtained by ultrafiltration of common bean seed extract in water turbidity removal. Ecological engineering, 49, 48-52.
[38] Liu, L., Zhang, B., Zhang, Y., He, Y., Huang, L., Tan, S., Cai, X. (2015). Simultaneous Removal of cationic and anionic dyes from environmental water using montmorillonite-pillared graphene oxide. Journal of chemical and engineering data, 60, 1270-1278.
[39] Duman, O., Ayranci, E. (2010). Adsorptive removal of cationic surfactants from aqueous solutions onto high-area activated carbon cloth monitored by in situ UV spectroscopy. Journal of hazardous materials, 174, 359-367.
[40] Beltrán-Heredia, J., Sánchez-Martín, J. (2009). Removal of sodium lauryl sulphate by coagulation/flocculation with Moringa oleifera seed extract. Journal of hazardous materials, 164, 713-719.
[41] Beltrán-Heredia, J., Sánchez-Martín, J., Frutos-Blanco, G. (2009). Schinopsis balansae tannin-based flocculant in removing sodium dodecyl benzene sulfonate. Separation and purification technology, 67, 295-303.