Separation of oily pollution from water and wastewater by low cost and reusable composite based on natural fibers

Mirzaei, Masoomeh

doi:10.22104/aet.2021.4906.1324

Separation of oily pollution from water and wastewater by low cost and reusable composite based on natural fibers

Document Type : Research Paper

Author

Masoomeh Mirzaei

Department of chemical engineering, Mahshahr branch, Islamic azad university, Mahshahr, Iran

10.22104/aet.2021.4906.1324

Abstract

In this study, the activated carbon powder treated on the natural cotton fibers by a solvo-thermal method. Acetone and hydrazine used as solvent. The porous, low cost and hydrocarbon loving adsorbents obtained. Ultrasonic waves applied for homogeneous distribution of powder. Adsorbent characterization performed by FTIR and SEM analysis. Batch adsorption experiments carried out to remove the spill of motor engine oil on the water. Adsorption, desorption and reuse of the adsorbent were done in 5 steps. The highest adsorption capacity was 40.2 g/g. After 5 replicate of adsorbent reuse, the adsorption efficiency and recovery percentage were about 90%. Continuous experiments performed by 500 ml of two petrochemical and refinery wastewater samples with 2 g of adsorbent at two different flowrates. The results showed that removal percentage of oil achieved to 96%, in the inlet concentration less than 40 g oil per each gram of adsorbent. By increasing the amount of inlet oil above 40 g/g, the adsorption efficiency decreased. For these wastewater, by increasing the amount of adsorbent from 2g to 3 g, the oil pollution was completely absorbed. Therefore, this composite with acceptable performance can use for spill remove and continuous removal of oil pollutions from water and wastewater

Keywords

Main Subjects

water and wastewater treatment

References

[1] Li, Y., Mei H., Fang H. (2017). A review of treating oily wastewater. Arabian journal of chemistry, 10, 1913-1922.

[2] Fan, C. Y., Krishnamurthy, S. (1995). Enzymes for enhancing bioremediation of petroleum-contaminated soils: a brief review. Journal of the air and waste management association, 45(6), 453-460.

ordered mesoporous carbon from aqueous solution: Equilibrium, thermodynamic and kinetics. Journal of colloid and interface science, 430, 272-282.

[3] Hua J. (2006). Biodegradation of dispersed marine fuel oil in sediment under engineered pre-spill application strategy. Ocean engineering, 33(1), 52-67.

[4] Domenico, P. A., Schwartz, F. W. (1998). Physical and chemical hydrogeology (Vol. 506). New York: Wiley.

[5] Xuebing H, Yun Y., Jianer Zh., Yongqing W., Jian L. (2015). The improved oil/water separation performance of graphene oxide modified Al₂O₃ microfiltration membrane. Journal of membrane science, 476, 200-204.

[6] Li Y., Chen H., Wang Q., Li G. (2021). Further modification of oil–water separation membrane based on chitosan and titanium dioxide. Journal of materials science: materials in electronics, 32, 4823-4832.

[7] Huang, Y., Li, H., Wang, L., Qiao, Y., Tang, C., Jung, C., Yu, M. (2015). Ultrafiltration membranes with structure‐optimized graphene‐oxide coatings for antifouling oil/water separation. Advanced materials interfaces, 2(2), 1400433.

[8] Kizil S., Sonmez H. B. (2017). Oil loving hydrophobic gels made from glycerol propoxylate: Efficient and reusable sorbents for oil spill clean-up. Journal of environmental management, 196, 330-339.

[9] Peng L., Yuan Sh., Yan G., Yu P., Luo Y. (2014). Hydrophobic sSponge for spilled oil absorption. Journal of applied polymer science, 10, 1-7.

[10] Hw J., Heo J., Jeon S., Park J. H., Kang H. W.(2019). Bio-inspired hollow PDMS sponge for enhanced oil–water separation, Journal of hazardous materials, 365. 494-501.

[11] Lin B., Chen J., Li Z., Fu-AnHe, HaoLi D. (2019). Superhydrophobic modification of polyurethane sponge for the oil-water separation, Surface and coatings technology, 359, 216-226.

[12] Hoai N., Sang N. N., Hoang T. D. (2017). Thermal reduction of graphene oxide coated cotton for oil and organic solvent removal. Material science and engineering, 8, 10-15.

[13] Pirooz M., Akbari N., Kamali M., Biria D., (2018) Investigation of the control of the fat, oil and grease in sewer lines and their removal by surfactant treatment. Advances in environmental technology, 3,155-161.

[14] Yang S., Chen L., Mua L., Ma P. C. (2014) Magnetic graphene foam for efficient adsorption of oil and organic solvents. Journal of colloid and interface science, 430, 337-344

[15] Lia Z. T., Wua H. T., Chena W. Y., Hea F., Li D. H. (2019). Preparation of magnetic superhydrophobic melamine sponges for effective oil-water separation. Separation and purification technology, 212, 40-50.

[16] Hafshejani, A. S., Hajiannia, A., Eslamian, S. (2017). Investigating the performance of Ogata-banks' one-dimensional dispersion equation in oil contamination dispersion in Bentonite soil. International journal of global energy issues, 40(6), 345-359..

[17] H. El-Naas M., Al-Zuhair S., Alhaija M. A.(2010). Reduction of COD in refinery wastewater through adsorption on date-pit activated carbon. Journal of hazardous materials, 173, 750-757.

[18] Wahi R., Chuah L. A., Shean T., Choong Y., Ngaini Z., Nourouzi M. M. (2013) Oil removal from aqueous state by natural fibrous sorbent: An overview. Separation and purification technology. 113, 51-63.

[19] Sabir, S. (2015). Approach of cost-effective adsorbents for oil removal from oily water. Critical reviews in environmental science and technology, 45(17), 1916-1945.

[20] Diraki, A., Mackey, H. R., McKay, G., Abdala, A. (2019). Removal of emulsified and dissolved diesel oil from high salinity wastewater by adsorption onto graphene oxide. Journal of environmental chemical engineering, 7(3), 103106.

[21] Kobya, M., Demirbas, E., Senturk, E., Ince, M. (2005). Adsorption of heavy metal ions from aqueous solutions by activated carbon prepared from apricot stone. Bioresource technology, 96, 1518–1521.

[22]VaseghianY.(2015).Modelingandoptimizationofoilrefinerywastewaterchemicaloxygendemandremovalindissolvedairflotationsystembyresponsesurfacemethodology. Advances in environmental technology, 3, 129-135.

[23] Godino-Salido L., Santiago-Medina M., Arranz-Mascarós A., López-Garzón P., Gutiérrez-Valero R., Melguizo M. D., López-Garzón F. J. (2014) Novel active carbon/crown ether derivative hybrid material for the selective removal of Cu(II) ions: The crucial role of the surface chemical functions. Chemical engineering science, 114, 94–104.

[24] Mohammad-Pajooh, E., Turcios, A. E., Cuff, G., Weichgrebe, D., Rosenwinkel, K. H., Vedenyapina, M. D., Sharifullina, L. R. (2018). Removal of inert COD and trace metals from stabilized landfill leachate by granular activated carbon (GAC) adsorption. Journal of environmental management, 228, 189-196.

[25] Fathy M., El-Sayed M., Ramzi M., Abdelraheem O.H. (2018). Adsorption separation of condensate oil from produced water using ACTF prepared of oil palm leaves by batch and fixed bed techniques. Egyptian journal of petroleum, 27(3), 319-326

[26] 5520 Oil and Grease, Standard Methods For the Examination of Water and Wastewater, DOI: 10.2105/SMWW.2882.107.