Facile synthesis of Ca-(OH)2-Mg nanocomposite and its applications for the removal of manganese from drinking water: A pilot study

Document Type : Research Paper

Authors

1 Department of Environmental, Water and Earth Science, Faculty of Science, Tshwane University of Technology, Private bag X680, Pretoria 0001, South Africa

2 Magalies Water, Scientific Services, Research and Development Division, Erf 3475, Stoffberg Street, Brits, 0250, South Africa

3 Department of Environmental Sciences, College of Agriculture and Environmental Sciences, University of South Africa (UNISA), P. O. Box 392, Florida, 1710, South Africa

Abstract

A pilot trial was performed in a potable water treatment plant with a capacity of 16 ML/day.  The aim was to determine the removal of manganese using a mechanochemically synthesized Mg-(OH)2-Ca nanocomposite. The acquired results were underpinned by state-of-the-art analytical instruments. Specifically, the trials were performed for 157 hr using hydrated lime, periclase, and their nanocomposite individually. The key performance indicators were manganese, turbidity, electrical conductivity (EC), and pH. The results showed an increase in pH from ±7.46 to ≥7.5, ≥8.2, and ≥7.8 and EC from ±0.24 to ≥0.28, ≥0.57, and ≥0.58 mS/cm for hydrated lime, periclase, and their nanocomposite, respectively. Manganese was reduced from ±400 to ≤80 µg/L, ≤89 µg/L, and ≤54 µg/L for hydrated lime, periclase, and their nanocomposite, respectively. The NTU was reduced to ≤1 for all the chemicals but registered the following sequence: ≤0.40, ≤0.85, and ≤0.89 for hydrated lime ≥ nanocomposite ≥ periclase, respectively, from 6.45 NTU. The findings of this study demonstrated the capabilities of nanomaterials in increasing the pH of the product solution and attenuating manganese and turbidity to the required levels. Lastly, the material costs denoted R 6300.00 (323.98 USD)/week for the nanocomposite, and this was cheaper when compared to individual materials. Interestingly, the nanocomposite denoted superior and cost-effective performance compared to individual materials and will be a great success for the attenuation of manganese and other contaminants, hence enhancing its ferocious versatility in water treatment.

Graphical Abstract

Facile synthesis of Ca-(OH)2-Mg nanocomposite and its applications for the removal of manganese from drinking water: A pilot study

Keywords

Main Subjects


[1] Patil, D., Chavan, S., Oubagaranadin, J. (2016). A review of tehnologies for manganese removal from wastewater. Environmental chemical engineering journal, 4(1), 468-487.
https://doi.org/10.1016/j.jece.2015.11.028.
[2] Akhtar, N., Syakir Ishak, M. I., Bhawani, S. A., Umar, K. (2021). Various natural and anthropogenic factors responsible for water quality degradation: A review. Water, 13, 2660.
https://doi.org/10.3390/w13192660
[3] Beduk, F., Aydin, S., Aydin, M., Bahadir, M., 2022. Consequences of heavy metals in water and wastewater for the environment and human health, in: Bahadir, M., Haarstrick, A. (Eds.), Water and Wastewater Management: Global Problems and Measures. Springer, Cham, pp. 221 - 228.
[4] Yang, H., Li, D., Zeng, H., Zhang, J. (2019a). Long-term operation and autotrophic nitrogen conversion process analysis in a biofilter that simultaneously removes Fe, Mn and ammonia from low-temperature groundwater. Chemosphere, 222, 407-414.
https://doi.org/10.1016/j.chemosphere.2019.01.143
[5] Yang, H., Li, D., Zeng, H., Zhang, J. (2019b). Impact of Mn and ammonia on nitrogen conversion in biofilter coupling nitrification and ANAMMOX that simultaneously removes Fe, Mn and ammonia. Science of total environment, 648, 955-961.
https://doi.org/10.1016/j.scitotenv.2018.08.223
[6] Kouzbour, S., El Azher, N., Gourich, B., Gros, F., Vial, C., Stiriba, Y. (2017). Removal of manganese (II) from drinking water by aeration process using an airlift reactor. Journal of water process engineering, 16, 233-239.
https://doi.org/10.1016/j.jwpe.2017.01.010
[7] Gerke, T., Little, B., Maynard, J. (2016). Manganese deposition in drinking water distribution systems. Science of the total environment, 541, 184 - 193.
https://doi.org/10.1016/j.scitotenv.2015.09.054
[8] Miah, M. R., Ijomone, O. M., Okoh, C. O. A., Ijomane, O. K., Akingbade, T. K., Krum, B., Martins Jr, A. C., Akinyemi, A., Aranoff, N., Soares, F. A. A., Bowman, A. B., Aschner, M. (2020). The effects of manganese overexposure on brain health. Neurochemistry international, 135, 104688.
https://doi.org/10.1016/j.neuint.2020.104688
[9] Cheng, Y., Xiong, W., Huang, T. (2021). Mechanistic insights into effect of storage conditions of Fe-Mn co-oxide filter media on their catalytic properties in ammonium-nitrogen and manganese oxidative removal. Separation and purification technology, 259, 118102.
https://doi.org/10.1016/j.seppur.2020.118102
[10] WHO., 2005. Manganese in drinking water: background document for development of WHO Guidelines for drinking-water quality.
[11] Ifeoluwa, O. B. (2019). Harmful effects and management of indiscriminate solid waste disposal on human and its environment in Nigeria: A review. Global journal of research and review, 6(1), 1 - 4.
[12] USEPA., 2004. Drinking water health advisory for manganese, U.S. Environmental Protection Agency Office of Water Washington, DC, USA: DC EPA-822-R-04-003.
[13] Marais, S. S., Ncube, E. J., Msagati, T. A. M., Mamba, B. B., Nkambule, T. T. I. (2019). Assessment of trihalomethane (THM) precursors using specific ultraviolet absorbance (SUVA) and molecular size distribution (MSD). Journal of water process engineering, 27, 143 - 151.
https://doi.org/10.1016/j.jwpe.2018.11.019
[14] Hoyland, V. W., Knocke, W. R., Falkinham III, J. O., Pruden, A., Singh, G. (2014). Effect of drinking water treatment process parameters on biological removal of manganese from surface water. Water research, 66, 31-39.
https://doi.org/10.1016/j.watres.2014.08.006
[15] Alvarez-Bastida, C., Martínez-Miranda, V., Solache-Ríos, M., Linares-Hernández, I., Teutli-Sequeira, A., Vázquez-Mejía, G. (2018). Drinking water characterization and removal of manganese. Removal of manganese from water. Journal of environmental chemical engineering, 6(2), 2119-2125.
https://doi.org/10.1016/j.jece.2018.03.019
[16] Carolin, C. F., Kumar, P. S., Saravanan, A., Joshiba, G. J., Naushad, M. (2017). Efficient techniques for the removal of toxic heavy metals from aquatic environment: A review. Journal of environmental chemical engineering, 5(3), 2782-2799.
https://doi.org/10.1016/j.jece.2017.05.029
[17] Livinalli, N. F., Silvestre, W. P., Duarte, J., Peretti, I., Baldasso, C. (2023). Study of reverse osmosis performance for iron and manganese removal from raw freshwater. Chemical Engineering communications, 210(11), 1961 - 1971.
https://doi.org/10.1080/00986445.2023.2169681
 [18] Shiba, N. (2015). Extraction and precipitation of phosphorus from sewage sludge [University of Johannesburg]. Johannesburg. https://ujcontent.uj.ac.za/vital/access/manager/Index?sitename=Research%20Output
[19] Keithley, A. E., Ryu, H., Gomez-Alvarez, V., Harmon, S., Bennett-Stamper, C., Williams, D., Lytle, D. A. (2023). Comprehensive characterization of aerobic groundwater biotreatment media. Water research, 230, 119587.
https://doi.org/10.1016/j.watres.2023.119587
[20] Dotto, G., McKay, G. (2020). Current scenario and challenges in adsorption for water treatment. Environmental chemistry engineering journal, 8(4), 103988.
https://doi.org/10.1016/j.jece.2020.103988
[21] Masindi, V., Foteinis, S., Renforth, P., Ndiritu, J., Maree, J. P., Tekere, M., Chatzisymeon, E. (2022). Challenges and avenues for acid mine drainage treatment, beneficiation, and valorisation in circular economy: A review. Ecological engineering, 183, 106740.
https://doi.org/10.1016/j.ecoleng.2022.106740
[22] Tobiason, J. E., Bazilio, A., Goodwill, J., Mai, X., Nguyen, C. (2016). Manganese removal from drinking water sources. Current pollution reports, 2(3), 168-177.
https://doi.org/10.1007/s40726-016-0036-2
[23] Kamal, N., Sulaiman, S. (2014). Bench-scale study of acid mine drainage treatment using localneutralisation agents. Malaysian journal of fundamental and aplied sciences, 10(3).
https://doi.org/10.11113/mjfas.v10n3.272
[24] Mulyadi, D., Haryati, S., Said, M. (2020). The Effect of calcium oxide and aluminum sulfate on Iron, manganese and color removal at peat water treatment. Indonesian journal of fundamental and applied chemistry, 5(2), 42-48.
http://dx.doi.org/10.24845/ijfac.v5.i2.42
[25] Abdel-Shafy, H. I. (2015). Chemical treatment for removal of heavy metals from industrial wastewater. Egypt journal of chemistry, 58(1), 1-12.
https://doi.org/10.21608/EJCHEM.2015.293
[26] Akbar, N. A., Aziz, H. A., Adlan, M. N. (2015). Iron and manganese removal from groundwater using high quality limestone. Applied mechanics and materials, 802, 460-465.
https://doi.org/10.4028/www.scientific.net/AMM.802.460
[27] Du, B., Hou, D., Duan, N., Zhou, C., Wang, J., Dan, Z. (2015). Immobilization of high concentrations of soluble Mn(II) from electrolyric manganese solid waste using inorganic chemicals. Environmrntal science and pollution research, 22, 7782-7793.
https://doi.org/10.1007/s11356-015-4197-0
[28] Zhang, Q., Zhong, S., Zhang, F., Zhang, Z., Wan, Y. (2019). Alkaline sustained-release material based on in situ manganese removal technology of groundwater. International journal of environmental research, 13, 661-668.
https://doi.org/10.1007/s41742-019-00204-w
[29] Geldenhuys, A. J., Maree, J. P., de Beer, M., Hlabela, P. (2003). An integrated limestone/lime process for partial sulphate removal. Journal of south African institute of mining and metallurgy, 103, 345-354.
https://hdl.handle.net/10520/AJA0038223X_2806
[30] Magagane, N., Masindi, V., Ramakokovhu, M. M., Shongwe, M. B., Muedi, K. L. (2019). Facile thermal activation of non-reactive cryptocrystalline magnesite and its application on the treatment of acid mine drainage. Journal of environmental management, 236, 499-509.
https://doi.org/10.1016/j.jenvman.2019.02.030
[31] Szymoniak, L., Claveau-Mallet, D., Haddad, M., Barbeau, B. (2022). Application of magnesium oxide media for remineralization and removal of divalent metals in drinking water treatment: A review. Water, 14, 633.
https://doi.org/10.3390/w14040633
[32] Srivastava, V., Sharma, Y. C., Sillanpää, M. (2015). Green synthesis of magnesium oxide nanoflower and its application for the removal of divalent metallic species from synthetic wastewater. Ceramics international, 41(5), 6702-6709.
https://doi.org/10.1016/j.ceramint.2015.01.112
[33] Macias, F., Caraballo, M. A., Rotting, T. S., Perez-Lopez, R., Nieto, J. M., Ayora, C. (2012). From highly polluted Zn-rich acid mine drainage to non-metallic waters: Implementation of a multi-step alkaline passive treatmentsystem to remediate metal pollution. Science of the total environment, 433, 323-330.
https://doi.org/10.1016/j.scitotenv.2012.06.
[34] Zendelska, A., Trajanova, A., Golomeova, M., Golomeova, B., Mirakovski, D., Doneva, N., Hadzi-Nikolova, M. (2022). Comparison of efficiencies of neutralizing agents for heavy metal removal from acid mine drainage. Journal of mining and environment, 13(3), 679-691.
https://doi.org/10.22044/jme.2022.12090.2205
[35] Calugaru, I. L., Thomas, G., Carmen, M. N., 2018. Treatment of manganese in acid and neutral mine drainage using modified dolomite, in: Brebbia, C. A. (Eds.), Water Studies. WIT Press, Boston, pp. 232-333.
[36] Le Bourre, B., Neculita, C., Coudert, L., Rosa, E. (2020). Manganese removal processes and geochemical behaviour in residues from passive treatment of mine drainage. Chemosphere, 259, 127424.
https://doi.org/10.1016/j.chemosphere.2020.127424
[37] Hu, H., Zhang, Q. (2021). Mechanochemical preparation of mineral based adsorbent and its effective purification ability for wastewater. KONA Power and particle journal, 38, 155-167.
https://doi.org/10.14356/kona.2021012
[38] Khusnutdinov, V. P., Isupov, V. P. (2008). Mechanochemical synthesis of a hydroxycarbonate form of layered magnesium aluminium hydroxides. Inorganic materials, 44, 263-267.
https://doi.org/10.1134/S0020168508030096
[39] Bester, K. M., Focke, W. W., Labuschangé, F. J. W. J. (2019). Mechanochemical synthesis of layered double hydroxides AIP Conference Proceedings.
[40] Eaton, A. D., Clesceri, L. S., Rice, E. W., Greenberg, A. E., 2005. Standard methods for the examination of water and wastewater. 21st Edn, American public health association press, Washington, DC.
[41] APHA., 2010. Standard Methods for the Examination of Water and Wastewater, in: Lipps, W. C., Baxter, T. E., Braun-Howland, E. (Eds.), American public health association, Washington, DC.
[42] Rice, E. W., 2017. Standard Methods for the Examination of Water and Wastewater, in: Baird, R. B., Eaton, A. D., Rice, E. W. (Eds.). 23rd Edn, American public health association, American water works association, Water environment federation, Washington D.C.
[43] SANS., 2015. Drinking water for SANS 241:2015. South Africa.
[44] Oustadakis, P., Agatzini-Leonardo, S., Tsakiridis, P. E. (2006). Nickel and cobalt precipitation from sulphate leach liquor using MgO pulp as neutralizing agent. Minerals engineering, 19, 1204-1211.
https://doi.org/10.1016/j.mineng.2005.11.006
[45] Navarro, A., Maetinez da Matta, M. I. (2022). Application of magnesium oxide for metal removal in mine water treatment. Sustainability, 14(23), 15857.
https://doi.org/10.3390/su142315857
[46] Mamakoa, E., Fosso-Kankeu, E., Masindi, V., Neomagus, H. (2022). Comparison of MgO and MgCo3 in the treatment of acid mine drainage international conference on science, engineering, Technology and water management (SETWM-20), Johannesburg (SA).
[47] WHO., 2017. Water quality and health review of turbidity: Information for regulators and water supply.
[48] Mann, A. G., Tam, C. C., Higgins, C. D., Rodrigues, L. C. (2007). The association between drinking water turbidity and gastrointestinal illness: a systematic review. BMC public health, 7(1), 256.
https://doi.org/10.1186/1471-2458-7-256
[49] Semerjian, L., Ayoub, G. (2003). High-pH-magnesium coagulation-flocculation in wastewater treatment. Advances in environmental research, 7(2), 389-403.
https://doi.org/10.1016/S1093-0191(02)00009-6
[50] Mirbagheri, S. A., Hosseini, S. N. (2004). Pilot plant investigation on petrochemical wastewater treatment for the removal of copper and chromium with the objective of reuse. Desalination, 171, 85-93.
https://doi.org/10.1016/j.desal.2004.03.022
[51] Agudosi, E., Abdullah, E., Mubarak, N., Khalid, M., Pudza, M., Agudosi, N., Abutu, E. (2018). Pilot study of in-line continuous flocculation water treatment plant. Journal of environmental chemical, 6(6), 7185-7191.
https://doi.org/10.1016/j.jece.2018.11.001
[52] Prazeres, A. R., Luz, S., Fernandes, F., Jeronimo, E. (2020). Cheese wastewater treatment by acid and basic precipitation: application of H2So4, HNO3, HCL, Ca(OH)2 and NaOH. Journal of environmental chemical engineering, 8(2), 103556.
https://doi.org/10.1016/j.jece.2019.103556
[53] Aguiar, A., Xavier, G., Ladeira, A. (2010). The use of limestone, lime and MnO2 in the removal of soluble manganese from acid mine drainage. 10th International Conference of Water Pollution: modelling, monitoring and management.
[54] Masindi, V., Akinwekomi, V., Maree, J. P., Muedi, K. L. (2017). Comparison of mine water neutralisation efficiencies of different alkaline generating agents. Journal of environmental chemical engineering, 5, 3903-3913.
https://doi.org/10.1016/j.jece.2017.07.062
[55] Silva, A. M., Cunha, E. C., Silva, F. D., Leão, V. A. (2012). Treatment of high-manganese mine water with limestone and sodium carbonate. Journal of cleaner production, 29, 11-19.
https://doi.org/10.1016/j.jclepro.2012.01.032
[56] Balladares, E., Jerez, O., Parada, F., Baltierra, L., Hernandez, C., Araneda, E., Parra, V. (2018). Neutralization and co-precipitation of heavy metals by lime addition to effluent from acid plant in a copper smelter. Minerals engineering, 122, 122-129.
https://doi.org/10.1016/j.mineng.2018.03.028
[57] Rout, C., Sharma, A. (2011). Assessment of drinking water quality: A case study of Ambala cantonment area, Haryana, India. International journal of environmental sciences, 2(2), 933-945.
[58] Apera, I. (2019). Conductivity pH DO ORP. Testing conductivity. https://support.aperainst.com
[59] Yan, B., Mai, G., Chen, T., Lei, C., Xiao, X. (2015). Pilot test of pollution control and metal resource recovery for acid mine drainage. Water science and technology, 72(12), 2308-2317.
https://doi.org/10.2166/wst.2015.429
[60] Liu, Y. N., Zhang, Z. S., Xia, J. P. (2013). Removal of iron in Nickel precipitation residue wastewater with magnesium oxide. Advanced materials research 634, 254-257.
https://doi.org/10.4028/www.scientific.net/AMR.634-638.254
[61] Vlyssides, A., Moutsatsou, A., Mai, S., Barampouti, E. M. (2003). Lime effect on sulphates and iron removal from wastewater of a sulphuric acid iron pickling process. Fresenius environmental bulletin, 12(10), 1276-1279.
[62] BrbootI, M. M., AbiD, B. A., Al-Shuwaiki, N. M. (2011). Removal of heavy metals using chemical precipitation. Engineering and technology, 29(3).
[63] Georgiou, D., Aivazidis, A., Hatiras, J., Gimouhopoulos, K. (2003). Treatment of cotton textile wastewater using lime and ferrous sulfate. Water research 37(9), 2248-2250.
https://doi.org/10.1016/S0043-1354(02)00481-5
[64] Mortula, M., Ali, T., & Elaksher, A. (2020). Municipal wastewater treatment using different coagulants. Desalination and water treatment 179, 8-18.
https://doi.org/10.5004/dwt.2020.24989
[65] Mehmood, K., Rehman, S. K. U., Wang, J., Farooq, F., Mahmood, Q., Jadoon, A. M., Javed, M. F., Ahmed, A. (2019). Treatment of pulp and paper industrial effluent using physicochemical process for recycling. Water, 11(11), 2393.
https://doi.org/10.3390/w11112393
[66] Uddin, M. M., Hasan, M. J., Islam, M. D., Rahaman, A., Shamsuddin, S. M. (2020). Removal of chromium(III) and other physical parameters from chrome tan wastewater and recovery of chromium from the precipitating sludge. Textile and leather review, 3(2), 64-77.
https://doi.org/10.31881/TLR.2020.07
[67] Ewerts, H., Venter, A., & Barnard, S. (2010). Effectiveness of purification processes in removing algae from Vaal Dam water at the Rand Water Zuikerbosch treatment plant in Vereeniging [North-West University].
[68] Polaczyk, A., Scarpino, P. V., Barth, E. (2002). Alkaline stabilization of reshwater sediments: Effectiveness of microbial population reduction [B.S Morehead State University].
[69] Nkele, K., Mpenyana-Monyatsi, L., Masindi, V. (2022). Fabrication of highly reactive MgO-NPs-CaO-hydrous nanocomposite and its application for the removal of manganese from aqueous solution. Advances in environmental technology, 8(4), 293-309.